光学
化学
光声效应
微探针
光纤
信号(编程语言)
光声光谱学
吸收(声学)
体积热力学
生物医学中的光声成像
分析化学(期刊)
物理
矿物学
色谱法
量子力学
计算机科学
程序设计语言
作者
Heng Wang,Yufu Xu,Jingya Zhang,Xinyu Zhao,Zhaodong Zhang,Ke Chen
标识
DOI:10.1021/acs.analchem.4c05486
摘要
A linear spot-type multipass cell-enhanced fiber-optic photoacoustic gas microprobe is proposed. To further reduce the volume of the gas chamber and enhance the photoacoustic signal, we designed the cross section of the photoacoustic tube as a slit with a height of 10 mm and a width of 1.5 mm. The volume of the gas chamber is only 210 μL. Through theoretical analysis and multiphysical field simulation, the photoacoustic intensity of the slit cross section is more than 6 times that of traditional circular cross section. A cantilever beam is integrated into the photoacoustic microprobe and forms a Fabry–Perot (FP) interferometer with an optical fiber, achieving enhanced photoacoustic detection. By adjusting the angle of the collimator, the light passes through the photoacoustic cell 26 times, and 13 linear spots are formed on the reflecting surface. The photoacoustic signal with multiple linear reflections is 12.4 times that of a single reflection. The gas enters the sensor in a freely diffused manner, and the response time of the sensing system is 54 s. When the averaging time is 400 s, the detection limit of the designed sensor for acetylene gas reaches 1.5 ppb. The minimum detectable absorption coefficient (αmin) and the normalized noise equivalent absorption coefficient (NNEA) are 1.7 × 10–8 cm–1 and 1.9 × 10–9 Wcm–1/Hz1/2, respectively.
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