检出限
煅烧
原位
环境化学
土霉素
地表水
污染
废水
化学
环境污染
环境科学
纳米技术
催化作用
材料科学
环境工程
色谱法
抗生素
有机化学
生态学
生物
生物化学
环境保护
作者
Cuizhu Sun,Chenguang Li,Meiting Guo,Xianghao Yang,Yadan Luo,Lingyun Chen,Hao Zheng,Shasha Zhao,Fengmin Li
标识
DOI:10.1016/j.jhazmat.2023.131946
摘要
Antibiotics such as tetracyclines (TCs) have become a major threat to ecosystem safety and human health, as their abuse has caused the occurrence and proliferation of antibiotic-resistant bacteria and genes. Currently, there is still a lack of convenient in situ methods for the detection and monitoring of TC pollution in actual water systems. This research reports a paper chip based on the complexation of iron-based metal organic frameworks (Fe-MOFs) and TCs for rapid and in situ visual detection of representative oxytetracycline (OTC) pollution in water environments. The optimized complexation sample NH2-MIL-101(Fe)− 350 obtained by calcination at 350 °C exhibited the highest catalytic activity and was then used for paper chip fabrication by printing and surface modification. Notably, the paper chip demonstrated a detection limit as low as 17.11 nmol L−1 and good practicability in reclaimed water, aquaculture wastewater, and surface water systems, with OTC recovery rates of 90.6–111.4%. More importantly, the presence of dissolved oxygen (9.13–12.7 mg L−1), chemical oxygen demand (0.52–12.1 mg L−1), humic acid (< 10 mg L−1), Ca2+, Cl–, and HPO42– (< 0.5 mol L−1) had negligible interference on the detection of TCs by the paper chip. Therefore, this work has developed a promising method for rapid and in situ visual monitoring of TC pollution in actual water environments.
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