锶
材料科学
硅酸盐
离子键合
离子电导率
矿物学
化学工程
离子
物理化学
有机化学
化学
电极
工程类
电解质
作者
Hera Tarique,Raza Shahid,Prabhakar Singh,Raghvendra Pandey,Prabhakar Singh
标识
DOI:10.1016/j.mtcomm.2024.108652
摘要
Extensive research has been carried out to search new electrolytes for Solid Oxide Fuel Cells (SOFCs) in order to reduce their operating temperature in the intermediate temperature range (500 ̊C < t < 800 ̊C) for wide commercialization. Recently, alkali doped strontium silicates materials have been reported to show adequate ionic conductivity in the intermediate temperature range. Hence, in the present work, we have tried to synthesize trimeric Sr3-3xNa3xSi3O9-δ (0.00 ≤ x ≤ 0.20; SNS) system and did a comprehensive study on this system to examine its applicability as a solid electrolyte for electrochemical devices such as IT-SOFCs. The SNS system was prepared via solid state reaction route and characterized by means of XRD, FT-IR and Raman spectroscopy to authenticate the structural phase formation and to gather its spectroscopic traits. The optical Energy band gap of the system was calculated by means of UV-Visible absorption spectroscopy. Surface morphology, microstructure and elemental confinement of the system was examined via Scanning Electron Microscopy (SEM) and Energy dispersive spectroscopy (EDX) techniques. The ionic transport study of the system has been conducted via AC conductivity analysis and Electrical Impedance Spectroscopy (EIS) technique. The highest total conductivity ~ 0.46×10-2 Scm-1 at 650 ºC was found for the composition Sr2.40Na0.60Si3O9-δ thru EIS method.
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