卟啉
光催化
共价键
还原(数学)
化学
中心(范畴论)
组合化学
拓扑(电路)
金属有机骨架
光化学
材料科学
有机化学
催化作用
结晶学
数学
几何学
吸附
组合数学
作者
Ying Gao,Senzhi Li,Lei Gong,Jing Li,Dongdong Qi,Liu Naifang,Yongzhong Bian,Jianzhuang Jiang
标识
DOI:10.1002/anie.202404156
摘要
The synthesis and characterization of porphyrin center regulated three-dimensional covalent organic frameworks with 2-fold interpenetrated scu or sqc topology have been investigated. These COFs exhibit unique structural features and properties, making them promising candidates for photocatalytic applications in CO2 reduction and artemisinin synthesis. The porphyrin center serves as an anchor for metal ions, allowing precise control over structures and functions of the frameworks. Furthermore, the metal coordination within the framework imparts desirable catalytic properties, enabling their potential use in photocatalytic reactions. Overall, these porphyrin center regulated metal-controlled COFs offer exciting opportunities for the development of advanced materials with tailored functionalities.
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