氢解
催化作用
化学
钨
甘油
氧化物
丙二醇
纳米颗粒
铂金
选择性
铂纳米粒子
无机化学
氧化铝
多相催化
氧化铝
化学工程
铝
有机化学
工程类
作者
Tomoo Mizugaki,Takayuki Yamakawa,R. Arundhathi,Takato Mitsudome,Koichiro Jitsukawa,Kiyotomi Kaneda
出处
期刊:Chemistry Letters
[Oxford University Press]
日期:2012-12-01
卷期号:41 (12): 1720-1722
被引量:60
摘要
Abstract Tungsten oxide-supported platinum nanoparticles containing aluminum oxide species (Pt–AlOx/WO3) act as a highly efficient heterogeneous catalyst for the hydrogenolysis of glycerol to 1,3-propanediol without any additives. High 1,3-propanediol selectivity was observed due to the concerted effect of the Pt nanoparticles, aluminum oxide, and tungsten oxide support. The Pt–AlOx/WO3 catalyst is reusable with maintaining its high catalytic performance.
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