环氧氯丙烷
聚乙烯醇
材料科学
电解质
聚合物
循环伏安法
化学工程
离子电导率
扫描电子显微镜
高分子化学
介电谱
电化学
复合材料
化学
电极
物理化学
工程类
作者
Chun‐Chen Yang,Syh‐Jae Lin,Sung-Ting Hsu
标识
DOI:10.1016/s0378-7753(03)00429-4
摘要
Alkaline SPE was obtained from a blend of polyvinyl alcohol (PVA) and poly(epichlorohydrin) (PECH), PVA–PECH, by a solution-cast technique. The PVA host polymer is blended with PECH polymer to provide a polymer electrolyte with improved chemical and mechanical properties. The ionic conductivity of the PVA–PECH polymer electrolytes is between 10−2 and 10−3 S cm−1 at room temperature when the blend ratio is varied from 1:0.2 to 1:1. The PVA–PECH polymer was characterized by means of scanning electron microscopy, X-ray diffraction, stress–strain test, cyclic voltammetry, and a.c. impedance spectroscopy. It is found that the polymer electrolytes exhibit good mechanical strength and excellent chemical stability. The electrochemical performance of solid-state Zn–air batteries with various types of the blended polymer electrolyte films is examined by a galvanostatic discharge method.
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