化学
反应性(心理学)
异戊二烯
范围(计算机科学)
机制(生物学)
有机化学
组合化学
药物化学
共聚物
病理
哲学
认识论
程序设计语言
替代医学
聚合物
医学
计算机科学
作者
Joachim Heinicke,Barbara Gehrhus,Susanne Meinel
标识
DOI:10.1016/0022-328x(94)84048-2
摘要
The silylenes MeSiCl, MeSiOMe and MeSiNMe2 can be thermally generated from disilanes and trapped by butadiene, isoprene and 2,3-dimethylbutadiene to give functionally-substituted silacyclopentenes. Some examples of cycloadditions to heterodienes are included to demonstrate the scope and mechanism of the reaction. The reactivity of 1-chloro-1-methyl-silacyclopent- 3-ene has been studied.
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