Embedded Ni nanoparticles in CeZrO2 as stable catalyst for dry reforming of methane

Ni nanoparticles embedded in CeO2 ([email protected]2) and CeZrO2 ([email protected]2) were synthesized by sol-gel method and compared with a Ni/CeO2 prepared by support impregnation. The performance of the catalysts was investigated for dry reforming of methane reaction. In situ XRD, XANES and TEM showed that Ni embedded in CeO2 improved the resistance to sintering along the reduction at 800 °C. Doping ceria with zirconia inhibited the growth of Ni particles and increased the oxygen mobility. SEM, TEM, Raman spectroscopy and TGA of the used catalysts after dry reforming of methane showed that carbon formation rate was significantly reduced for the catalysts containing Ni nanoparticles embedded in ceria structure. Carbon deposits were not detected over [email protected]2 after 24 h of reaction. Therefore, the control of Ni particle size and the high oxygen mobility of [email protected]2 catalyst inhibited carbon deposition and favored the mechanism of carbon removal, promoting catalyst stability.