Development of novel collagen hydrolysate bio-nanocomposite films extracted from hide trimming wastes reinforced with chitosan nanoparticles

The wide availability of pollutant by-products from the leather industries has been a key factor in driving the research into converting these low-cost by-products into high value-added collagen-based products. In this study, collagen hydrolysate (CH) was extracted from hide trimming waste from the tanneries and used to prepare biodegradable films with chitosan nanoparticles (CNPs) with different concentrations to develop an alternative product to non-biodegradable plastics. The effects of CNPs concentration on the thickness, mechanical, water barrier, thermal, light transmittance, color properties, and opacity of CH-based films were investigated. The results clearly show that the tensile strength and elastic modulus values of CH/CNPs films increase significantly as the concentration of CNPs increases, while the elongation at break, water solubility, and water vapor permeability values decrease. In addition, scanning electron microscopy (SEM) showed uniform distributions of CNPs in the CH-based films. Based on the results obtained, the extraction of CH from hide trimming wastes and reuse in the production of biodegradable films will both prevent these valuable wastes from being dispose into the landfills and will be an alternative to fossil-derived plastics in the future.