凝聚态物理
材料科学
热电效应
塞贝克系数
极化子
声子
电阻率和电导率
声子散射
兴奋剂
热电材料
载流子
带隙
热导率
热传导
作者
Yu Liu (刘育),Zhixiang Hu (胡之翔),Milinda Abeykoon,Eli Stavitski,Klaus Attenkofer,Eric D. Bauer,Cedomir Petrovic
出处
期刊:Physical Review B
[American Physical Society]
日期:2021-06-14
卷期号:103 (24): 245122-
标识
DOI:10.1103/physrevb.103.245122
摘要
We carried out a comprehensive study of the structural, electrical transport, thermal, and thermodynamic properties in ferrimagnetic ${\mathrm{Mn}}_{3}{\mathrm{Si}}_{2}{\mathrm{Te}}_{6}$ single crystals. Mn and Te $K$-edge x-ray absorption spectroscopy and synchrotron powder x-ray diffraction were measured to provide information on the local atomic environment and the average crystal structure. The dc and ac magnetic susceptibility measurements indicate a second-order paramagnetic to ferrimagnetic transition at ${T}_{c}\ensuremath{\sim}74$ K, which is further confirmed by the specific heat measurement. ${\mathrm{Mn}}_{3}{\mathrm{Si}}_{2}{\mathrm{Te}}_{6}$ exhibits semiconducting behavior along with a large negative magnetoresistance of $\ensuremath{-}87%$ at ${T}_{c}$ and a relatively high value of thermopower up to $\ensuremath{\sim}10$ mV/K at 5 K. Besides the rapidly increasing resistivity $\ensuremath{\rho}(T)$ and thermopower $S(T)$ below 20 K, the large discrepancy between the activation energy for resistivity ${E}_{\ensuremath{\rho}}$ and thermopower ${E}_{S}$ above 20 K indicates the polaronic transport mechanism. Furthermore, the thermal conductivity $\ensuremath{\kappa}(T)$ of ${\mathrm{Mn}}_{3}{\mathrm{Si}}_{2}{\mathrm{Te}}_{6}$ is notably rather low, comparable to ${\mathrm{Cr}}_{2}{\mathrm{Si}}_{2}{\mathrm{Te}}_{6}$, and is strongly suppressed in the magnetic field across ${T}_{c}$, indicating the presence of strong spin-lattice coupling, also similar with ${\mathrm{Cr}}_{2}{\mathrm{Si}}_{2}{\mathrm{Te}}_{6}$.
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