烷基化
钳子运动
催化作用
化学
铬
酮
氯化物
金属
药物化学
有机化学
作者
Himani Narjinari,Niharika Tanwar,Lakshay Kathuria,Raksh V. Jasra,Akshai Kumar
摘要
β-Alkylation of alcohols has been efficiently accomplished using readily available 3d metal Cr under microwave conditions in air. Well-defined molecular Cr is involved with a KIE of 7.33 and insertion of α-alkylated ketone into Cr–H bond as the RDS.
科研通智能强力驱动
Strongly Powered by AbleSci AI