六氟磷酸盐
化学
支柱
氯仿
晶体结构
铵
Crystal(编程语言)
结晶学
分子
立体化学
有机化学
离子液体
催化作用
程序设计语言
工程类
结构工程
计算机科学
作者
Chengyou Han,Fengying Ma,Zibin Zhang,Binyuan Xia,Yihua Yu,Feihe Huang
出处
期刊:Organic Letters
[American Chemical Society]
日期:2010-09-10
卷期号:12 (19): 4360-4363
被引量:237
摘要
DIBPillar[n]arenes (n = 5, 6) were synthesized. They showed different host−guest properties with n-octyltriethyl ammonium hexafluorophosphate G due to their different cavity sizes. DIBpillar[5]arene showed no complexation with G, while DIBpillar[6]arene formed a 1:1 complex with G with an association constant of 334 (±24) M−1 in chloroform. In this letter, the first pillar[6]arene crystal structure and the first investigation of the host−guest chemistry of pillar[6]arenes are reported.
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