光催化
异质结
催化作用
煅烧
石墨氮化碳
降级(电信)
可见光谱
材料科学
化学工程
热液循环
电子转移
亚甲蓝
水溶液
氮化碳
比表面积
氧化还原
纳米技术
光化学
化学
光电子学
有机化学
计算机科学
电信
工程类
冶金
作者
Jiayi Wang,Pengfei Ren,Yanli Du,Xueyan Zhao,Zhengyan Chen,Peng Lü,Yanling Jin
标识
DOI:10.1016/j.jallcom.2023.169659
摘要
Graphitic carbon nitride (g-C3N4) is a promising photocatalyst with lots of merits, such as visible light driven (200–1000 nm), cost-effective and high stability. However, the single g-C3N4 photocatalyst is limited in its performance due to the high complexation rate of photogenerated electrons and holes and the confined specific surface area. Herein, a S-scheme heterojunction catalyst involving tubular g-C3N4 (TCN) and TiO2 is designed and constructed via precursor reforming strategy with subsequent hydrothermal calcination process. The tubular structure offers more active centers, conducive to light absorption and contact with pollutants, while the heterojunction facilitates the transfer and separation of electrons and holes. Thus, the TCN/TiO2 catalyst exhibits excellent photocatalytic activity with degradation efficiencies for methylene blue (MB) and tetracycline (TC) reaching 96.6 % and 100 %, respectively, as well as high degradation efficiency for other dyes (Congo red and Eosin y). Besides, TCN/TiO2 catalyst demonstrates outstanding stability and potential for practical application. An innovative S-scheme heterojunction system has shown remarkable potential for improving the separation and transferring electron-hole pairs, as well as delivering stronger redox capability. This work provides a promising strategy for the preparation of g-C3N4/TiO2 catalyst for the effective treatment of contaminated water.
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