催化作用
金属有机骨架
电催化剂
纳米技术
材料科学
光催化
多相催化
化学
吸附
有机化学
物理化学
电化学
电极
作者
Baghendra Singh,Apparao Draksharapu
标识
DOI:10.1002/cssc.202500750
摘要
High‐entropy metal‐organic framework (HE‐MOF) and their derived materials are a novel class of multipurpose materials with enormous catalytic potential. By incorporating multiple metal sites into a single MOF structure, HE‐MOFs offer tunable electronic structures, diverse active sites, and enhanced stability‐key attributes for catalytic applications. This review article presents a complete examination of current progress in HE‐MOFs and their derived materials for diverse catalytic reactions, including electrocatalysis, photocatalysis, and thermal catalysis. Various strategies for boosting the catalytic reactivity of HE‐MOFs and their derived materials have been discussed, including pore architecture modulation, morphological control, defect engineering, elemental composition tuning, and interface optimization. A thorough investigation is conducted on various catalytic reactions like water splitting, oxygen reduction, nitrogen reduction, alcohol oxidation, hydrogenation, and cycloaddition. Furthermore, we discuss the underlying structure‐property correlation governing their activity and highlight key challenges and future directions in this rapidly evolving field. The insights presented in this review aim to guide the rational design of next‐generation high‐entropy materials for sustainable and efficient catalytic processes.
科研通智能强力驱动
Strongly Powered by AbleSci AI