阳极
石墨
离子
异质结
材料科学
储能
锂(药物)
球磨机
纳米技术
化学工程
电极
化学
光电子学
复合材料
有机化学
物理化学
医学
功率(物理)
物理
量子力学
工程类
内分泌学
作者
Haiting Shi,Shuo Wang,Yuanhua Xia,Xuemei Yan,Daoxi Wang,Yaru Yin,Ping Huai,Zhiwei Xu,Chunying Min,Shengkai Liu,Xiaoqing Wu
出处
期刊:ACS applied energy materials
[American Chemical Society]
日期:2022-05-25
卷期号:5 (6): 7308-7316
被引量:8
标识
DOI:10.1021/acsaem.2c00828
摘要
Sodium-ion batteries (SIBs) have attracted significant attention as promising next-generation energy storage devices. However, the research and development of SIBs are still in their infancy due to the lack of suitable high-performance anode materials. As a commercial anode material for lithium-ion batteries (LIBs), graphite often shows a low sodium storage capacity. Herein, a graphite heterojunction material was prepared through a facile ball-milling method. During the ball-milling process, a defect-enriched g-C3N4/graphite heterojunction was formed and the nitrogen-containing functional groups were regulated, which promoted the sodium storage capacity. The resulting g-C3N4/graphite electrode can exhibit excellent long cycle stability and rate performance, delivering a high reversible capacity of 202 mAh g–1 at 1.0 A g–1 after 6000 cycles and 90.06 mAh g–1 at 5.0 A g–1 after 10000 cycles. Moreover, an ultrahigh rate capability can also be obtained at 1.0 A g–1 with a capacity of 111 mAh g–1. The superiority of heterostructures for sodium storage and diffusion was proved via DFT calculations, which verified the synergistic effect between graphite and g-C3N4. This study provides a simple and efficient method for preparing g-C3N4/graphite heterostructures as well as a deep insight into the sodium storage mechanism of a heterostructure anode.
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