催化作用
电子顺磁共振
化学
降级(电信)
阿特拉津
激进的
复合数
氧化还原
反应速率常数
核化学
猝灭(荧光)
动力学
无机化学
荧光
有机化学
材料科学
杀虫剂
物理
生物
复合材料
电信
量子力学
核磁共振
计算机科学
农学
作者
Jun Li,Ge Gou,Hailing Zhao,Chao Liu,Naiwen Li,Longguo Li,Bo Tan,Bo Lai
标识
DOI:10.1016/j.cej.2022.134840
摘要
CoFe2O4-CeO2 composites with different CoFe2O4 content were synthesized and used as catalysts for peroxymonosulfate (PMS) activation in water purification. Under the conditions of 200 mg/L 15%CoFe2O4-CeO2 and 0.15 mM PMS, complete atrazine degradation was achieved in the 15%CoFe2O4-CeO2/PMS system. The pseudo-first-order rate constant (kobs) in 15%CoFe2O4-CeO2/PMS system (0.224 min−1) was 2.4 and 4.8 times of that in CoFe2O4/PMS system (0.092 min−1) and (CoFe2O4 + CeO2)/PMS system (0.047 min−1). The main reactive species were verified through various quenching experiments and electron paramagnetic resonance tests, and the concentration of two main radicals was calculated. In addition, the interaction between CoFe2O4 and CeO2 involving Co(III)/Co(II), Fe(III)/Fe(II), and Ce(IV)/Ce(III) redox recycle for accelerating the degradation of organic compounds was explored. In addition, different from Cl−, HCO3− and NO3−, H2PO4− could promote atrazine degradation in 15%CoFe2O4-CeO2/PMS system by improving sulfate radical concentration in the reaction system. The main degradation intermediates of atrazine in the 15%CoFe2O4-CeO2/PMS and CoFe2O4/PMS systems were compared, as well as the degradation pathways. The toxicity analysis based on luminescent bacteria Vibrio fischeri indicated the superiority of 15%CoFe2O4-CeO2/PMS than CoFe2O4/PMS systems for ATZ degradation.
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