催化作用
钴
双功能
钙钛矿(结构)
氧化物
铜
氧化钴
材料科学
阴极
价(化学)
无机化学
氧化铜
兴奋剂
燃烧
催化燃烧
化学工程
化学
冶金
有机化学
物理化学
工程类
光电子学
作者
Yue Lv,Zhixing Li,Yan Yu,Jinling Yin,Kefan Song,Bingqian Yang,Lefan Yuan,Xiulan Hu
标识
DOI:10.1016/j.jallcom.2019.06.114
摘要
Copper/cobalt-doped perovskite oxide LaMn0.8M0.2O3 (M = Cu, Co) composites are synthesized through gel combustion with urea as the chelating agent and fuel. Both LaMn0.8Cu0.2O3 and LaMn0.8Co0.2O3 exhibit better catalytic performances for OER and ORR than LaMnO3 in alkaline media due to the abundance of oxygen vacancies and Mn4+ caused by the substitution of different valence elements. When used as a cathode catalyst in Li-O2 batteries, LaMn0.8Co0.2O3 can perform 91 stable cycles at 100 mA g−1 and the discharge specific capacity can reach up to 9620 mA h g−1 at 500 mA g−1. LaMn0.8Co0.2O3 has a longer cycle life and larger discharge capacity compared to LaMnO3 and LaMn0.8Cu0.2O3.
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