半胺
化学
有机化学
组分(热力学)
醛
酒
乙醚
催化作用
组合化学
热力学
物理
作者
Álvaro Beltrán,Eleuterio Álvarez,M. Mar Dı́az-Requejo,Pedro J. Pérez
标识
DOI:10.1002/adsc.201500588
摘要
Abstract The reaction of aldehydes, amines and alcohols usually leads to a series of equilibria from which isolation of one product is difficult to achieve. We have found that this three‐component reaction can be controlled and directed in an exclusive manner toward the formation of the hemiaminal ether. A series of 33 hemiaminal ethers has been obtained in high yields, from different aldehydes, amines and alcohols, under very mild conditions just with molecular sieves as promoter. magnified image
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