废止
化学
催化作用
亲核细胞
药物化学
表面改性
氧化还原
光化学
立体化学
组合化学
有机化学
物理化学
作者
Wei Yang,Jingyi Wang,Zhonglin Wei,Qian Zhang,Xianxiu Xu
标识
DOI:10.1021/acs.joc.5b02903
摘要
A temperature-dependent redox-neutral Rh(III)-catalyzed C-H bond annulation of N-methoxybenzamides with quinones was developed for the chemoselective synthesis of hydrophenanthridinones and phenanthridinones. This reaction involves an Rh(III)-catalyzed C-H bond functionalization and a subsequent cyclization through the directing group nucleophilic addition to the carbonyl group at room temperature.
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