对映选择合成
化学
有机催化
催化作用
艾伦
组合化学
有机化学
有机合成
生化工程
工程类
作者
Xing Wang,Xuling Chen,Wei Lin,Pengfei Li,Wenjun Li
标识
DOI:10.1002/adsc.202200085
摘要
Axially chiral allenes occur on a wide range of natural products and synthetic molecules with significant biological activity. Furthermore, they are versatile building blocks in organic synthesis because of their inherent chemical properties. Accordingly, catalytic enantioselective synthesis of axially chiral allenes has been paid much attention. Benefited from the development of asymmetric organocatalysis, many simple and efficient methods in terms of different catalytic systems as well as reaction partners have been developed. This review will focus on the recent progress in the field of organocatalytic enantioselective synthesis of allenes (2000–2022), which is organized according to types of allenes and the catalyst system used.
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