Superhigh-Luminance Ce:YAG Phosphor in Glass and Phosphor-in-Glass Film for Laser Lighting

荧光粉 材料科学 色度 激光器 光电子学 亮度 发光效率 光学 蓝光激光器 色温 光电效应 制作 量子效率 二极管 纳米技术 物理 医学 替代医学 图层(电子) 病理
作者
Shuyang Bao,Yueyuan Liang,Liansheng Wang,Luhan Wang,Xu Li,Yu Wang,Xiaojuan Liang,Weidong Xiang
出处
期刊:ACS Sustainable Chemistry & Engineering [American Chemical Society]
卷期号:10 (24): 8105-8114 被引量:103
标识
DOI:10.1021/acssuschemeng.2c02657
摘要

Solid laser lighting with high photoelectric conversion efficiency and compact size has been increasingly vital in lighting applications. Extensive research has been conducted to obtain high-quality color converters for application to high-power and high-luminance laser lighting. Currently, Y 3 Al 5 O 12:Ce 3+ phosphor in glass (Ce:PiG) and Y 3 Al 5 O 12:Ce 3+ phosphor-in-glass film (Ce:PiF) possessing high efficiency, low cost, easy fabrication, and controllable chromaticity are becoming the most mainstream research directions. In this study, by modifying the glass particle size and sintering temperature, investigating the relevant host glass, and so forth, high-performance Ce:PiG was developed through a one-step co-sintering technology. It possesses a high internal quantum efficiency, approaching 100% of the original phosphors (92.5%). The luminous efficacy (LE) of the Ce:PiG was 240 lm/W at 2.18 W/mm 2 under 450 nm blue laser diode (LD) excitation, which is the best result yet reported. Furthermore, to enhance the laser saturation threshold, the fabricated Ce:PiF relying on a sapphire substrate can withstand an 8 W/mm 2 blue incident power density. The obtained sample can even reach an LE of 251.5 lm/W, which is an obvious improvement to Ce:PiG. In addition, the result, an LD module combined with the sample that meets the standard white light source, indicates that this work has good prospects for white laser lighting.
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