电催化剂
材料科学
三元运算
石墨烯
锡
催化作用
化学工程
电化学
多硫化物
纳米技术
异质结
氧化还原
电极
化学
光电子学
计算机科学
电解质
工程类
物理化学
生物化学
冶金
程序设计语言
作者
Jingsheng Cai,Zhongti Sun,Wenlong Cai,Nan Wei,Yuxin Fan,Zhongfan Liu,Qiang Zhang
标识
DOI:10.1002/adfm.202100586
摘要
Designing high-performance electrocatalysts for boosting aprotic electrochemistry is of vital importance to drive longevous Li–S batteries. Nevertheless, investigations on probing the electrocatalytic endurance and protecting the catalyst activity yet remain elusive. Here, a ternary graphene-TiO2/TiN (G-TiO2/TiN) heterostructure affording conformal graphene chainmail is presented as an efficient and robust electrocatalyst for expediting sulfur redox kinetics. The G-TiO2/TiN heterostructure synergizes adsorptive TiO2, catalytic TiN, and conductive graphene armor, thus enabling abundant anchoring points for polysulfides and sustained active sites to allow smooth bi-directional electrocatalysis. Encouragingly, in situ crafted graphene chainmail ensures favorable protection of inner TiO2/TiN to retain their catalytic robustness towards durable sulfur chemistry. As expected, sulfur cathodes mediated by ternary G-TiO2/TiN harvest an impressive rate capability (698.8 mAh g−1 at 5.0 C), favorable cycling stability (a low decay of 0.054% per cycle within 1000 cycles), and satisfactory areal capacity under elevated loading (delivering 8.63 mAh cm−2 at a sulfur loading of 10.4 mg cm−2). The ternary heterostructure design offers an in-depth insight into the electrocatalyst manipulation and protection toward long lifespan Li–S batteries.
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