腐蚀
材料科学
涂层
介电谱
冶金
导电体
缓蚀剂
镍
塔菲尔方程
防腐
镀锌
电化学
复合材料
化学工程
钝化
作者
Zesong Gao,Xinhua Zhang,Yitong Tan,Dong Yang,Linrui Ma,Jianjia Shen,Qiangqiang Liao
出处
期刊:Protection of Metals and Physical Chemistry of Surfaces
[Springer Nature]
日期:2021-05-01
卷期号:57 (3): 570-578
标识
DOI:10.1134/s2070205121030114
摘要
Anticorrosive conductive coatings were prepared by adding solvents, dispersants, nickel powders, etc. to acrylic resin coatings with high viscosity, and conductive coatings were prepared on the surface of Q235 steel. The effects of nickel powder contents on the corrosion resistance of the conductive coating were investigated in a red soil solution, for which electrochemical impedance spectroscopy, Tafel polarization curve and corrosion morphology analysis were used. Adding different concentrations of Fe2(SO4)3 to the red soil solution, the effect of Fe2(SO4)3 content on the corrosion resistance of the conductive coating was studied. The results show that anti-corrosion performance of the coating material is variable according to the degree of hydrolysis. Besides, the content of nickel powder and Fe2(SO4)3 is also related to the anti-corrosion performance. The higher the content of nickel powder, the worse the corrosion resistance. The higher the content of Fe2(SO4)3 in the red soil solution, the lower the coating impedance and the worse the corrosion resistance. Fe2(SO4)3 will accelerate the corrosion reaction. A Fe2(SO4)3 catalyzed kinetic mechanism is advanced to expound accelerated corrosion process.
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