纳米颗粒
锌
吸附
结晶度
光催化
久效磷
污染物
核化学
降级(电信)
化学
环境化学
化学工程
材料科学
杀虫剂
纳米技术
有机化学
催化作用
工程类
农学
生物
电信
计算机科学
结晶学
作者
Bharti Bharti,J. S. Jangwan,Goutam Kumar,Vivek Kumar,Amrish Kumar
标识
DOI:10.1007/s42452-021-04294-0
摘要
Abstract ZnO nanoparticles have been synthesized and applied for the removal of different environmental pollutants in the present study. Combustion method is used for the preparation of ZnO NPs. X-Ray diffraction pattern reveals the crystallinity of the nanoparticles, where SEM and TEM images displayed that ZnO NPs were of size less than 100 nm and nearly spherical in shape. UV–Vis and IR spectra revealed the formation of ZnO NPs. Adsorption and advanced oxidation processes were employed for the removal/degradation of trace elements/pesticide. UV reactor containing 1 UV rod of 11 W (Philips) was used for the photocatalytic degradation of pesticide. ICP–OES and GC–MS techniques were used for the further quantitative analysis of trace elements and OP pesticide—monocrotophos, respectively. The analysis shows the 88% degradation of monocrotophos when subjected to UV light in the reaction chamber for 120 min at a pH 4 when 2 g of nanocatalyst is applied. However, the removal of trace element Arsenic shows linear adsorption as compared to Cd and Se. The removal efficiency of ZnO nanoparticles for Cd and Se was 36% and 64%, respectively, after 120 min. The synthesized nanoparticles are more effective than the commercially available ones.
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