软硬酸碱理论
金属有机骨架
化学
吸附
硫黄
表面改性
纳米技术
有机合成
组合化学
有机化学
材料科学
催化作用
物理化学
作者
Xianjiang Li,Wen Ma,Hongmei Li,Qinghe Zhang,Huwei Liu
标识
DOI:10.1016/j.ccr.2020.213191
摘要
Metal-organic frameworks (MOFs) are a class of crystalline inorganic-organic hybrid porous materials. Sulfur-functionalized MOFs (S-MOFs) are a subclass of MOFs that show some distinctive advantages and extensively studied in solid-phase extraction. In this review, we present a summary on the synthesis and adsorptive application of S-MOFs, and highlight the benefits of sulfur-functionalization. Three most widely used synthesis strategies, namely direct synthesis, post-synthetic modification and composite materials are developed to prepare S-MOFs. Based on hard-soft-acid-base (HSAB) theory, S-MOFs find practical applications in the adsorption of heavy metal ions, especially for mercury. Besides, efficient adsorption of inorganic non-metallic compounds and organic molecules is also reported. Finally, challenges and further perspectives of S-MOFs are presented and discussed in detail to achieve better advancement.
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