Surfactant-free emulsion of epoxy resin/sodium alginate for achieving robust underwater superoleophobic coating via a combination of phase separation and biomineralization

Underwater superoleophobic coatings exhibit promising prospects in the field of oil contamination resistance. However, their poor durability, stemming from the fragile structures and unstable hydrophilicity, greatly restricted their development. In this report, we proposed a novel strategy of combination water-induced phase separation and biomineralization to prepare the robust underwater superoleophobic epoxy resin-calcium alginate (EP-CA) coating by utilizing a surfactant-free emulsion of epoxy resin/sodium alginate (EP/SA). The EP-CA coating not only exhibited excellent adhesion to various substrates, but also had remarkable resistance to the physical/chemical attacks such as abrasion, acid, alkali and salt. It could also protect the substrate (e.g., PET substrate) from the damage of organic solution and the fouling of crude oil. This report provides a new perspective to fabricate robust superhydrophilic coating with a facile way.