氧化还原
化学
电化学
插层(化学)
钠
钠离子电池
离子
阴极
快离子导体
无机化学
相(物质)
反应机理
分析化学(期刊)
电解质
电极
物理化学
催化作用
有机化学
法拉第效率
作者
Dongxiao Wang,Na Su,Zhuo-Er Yu,Shigang Lu,Yingchun Lyu,Bingkun Guo
标识
DOI:10.1016/j.elecom.2023.107651
摘要
NASCION-type Na4MnV(PO4)3/C was synthesized through a sol-gel method. Two Na+ ions can reversibly (de)intercalation from/into the unit structure, with a reversible capacity of 106.7 mAh g-1. The charge-discharge curves show a voltage slope at 3.4 V, and a plateau at 3.6 V. To elucidate the sodium storage mechanisms, the structure evolution and electron transfer are demonstrated using in-situ X-ray diffraction and ex-situ X-ray absorption spectroscopy. It is found that at different stage of the electrochemical process, it undergoes different phase reaction process with different redox couples. A single-phase reaction occurs when the first sodium-ion extracted from Na4MnV(PO4)3 with a V3+/V4+ redox, while a two-phase reaction takes place when the second sodium-ion extracted with a Mn2+/Mn3+ redox. Galvanostatic intermittent titration technique, GITT, indicates the single-phase reaction process shows a faster kinetic compared to the two-phase reaction process. These findings between the kinetics, chemical and structural evolution provide new insight into the sodium storage mechanisms of NASICON-type cathode, and further the understanding of other materials for sodium-ion batteries.
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