铕
配位聚合物
发光
配体(生物化学)
聚合物
磺胺嘧啶
化学
螯合作用
配位复合体
选择性
材料科学
无机化学
有机化学
抗生素
光电子学
受体
金属
催化作用
生物化学
作者
Hui Min,Zhuo-hang Zhu,Yong‐Ki Min,Binling Yao,Peng Cheng
标识
DOI:10.1002/cplu.202400038
摘要
Abstract Sulfadiazine (SFZ) is an inexpensive large‐consumption antibiotic used for treat bacterial infections but an excess of residues in food can be harmful. Fast and specific luminescence detection of SFZ is highly challenging because of the interference of structurally similar antibiotics. In this work, we develop a two‐dimensional europium‐organic coordination polymer with excellent luminescence and water stability for highly specific detection of SFZ in the range of 0–0.2 mM. Structural analysis shows that the high stability of coordination polymer is due to the high coordination number of europium ion and the special chelating coordination structure of ligand. The experiment results revealed that the high selectivity and effectively luminescence quenched behaviour of coordination polymer toward SFZ is caused by highly efficient inner filter effect.
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