双金属
材料科学
复合数
锡
光热治疗
热稳定性
能量转换效率
热能储存
化学工程
纳米颗粒
纳米复合材料
相变材料
复合材料
纳米技术
热的
冶金
光电子学
生态学
工程类
生物
物理
气象学
作者
Ziheng Wu,Zhaochun Ye,Shasha Shi,Yaobing Fang,Li Li,Wancheng Yuan
标识
DOI:10.1016/j.solmat.2022.112019
摘要
Shape stability and excellent photothermal conversion performance are critical for composite PCMs in the field of solar energy utilization. This study prepares a nickel and cobalt-based bimetal organic framework (Ni–Co-BTC) which is further employed as the supporting material for 1-octadecanol (OD). The flower-like Ni–Co-BTC with an interconnected network exhibits large specific surface area, pore volume, and appropriate pore size distribution, which is conducive to the encapsulation of OD (up to 70 wt%). In addition, TiN nanoparticles are added to enhance the photothermal conversion performance of composite PCM. Therefore, the obtained OD/Ni–Co-BTC/TiN composite PCM exhibits considerable thermal energy storage capacity (145.8 J/g) and remarkable photothermal energy conversion efficiency (up to 97.75%). Furthermore, the composite PCM has outstanding thermal stability and reliability, and the phase change enthalpy is reduced by only 1.7% after 100 cycles. Accordingly, the composite PCM shows a promising application potential in solar energy harvesting, conversion and storage.
科研通智能强力驱动
Strongly Powered by AbleSci AI