Nanofiber derived MXene composite paper for electromagnetic shielding and thermal management

Despite the urgent demands in protecting wearable electronics from electromagnetic interference (EMI) in various conditions, it remains challenging to attain mechanically robust and flexible materials with both excellent EMI shielding and thermal managing performance. Herein, we report MXene composite paper that can provide multifunction with superior mechanical properties. To construct a hierarchical composite with 2D/0D reinforcements, the MXene paper is fabricated by hot pressing of electrospun Poly (vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) nanofibers incorporated with MXene nanosheets and carbon black nanoparticles. Due to the laminated structure connected by nanoparticles, the flexible composite paper shows remarkable mechanical strength and fatigue resistance that can provide stable EMI shielding effectiveness of 500 dB/mm even after 10000th cyclic rolling. Moreover, the high in-plane electrical conductivity and out-of-plane thermal conductivity allow a fast electrothermal heating and cooling behavior, which qualifies the MXene paper as multifunctional surface for wearable electronics.