Nanowires Framework Supported Porous Lotus‐Carbon Anode Boosts Lithium‐Ion and Sodium‐Ion Batteries

Abstract The novel design of carbon materials with stable nanoarchitecture and optimized electrical properties featuring simultaneous intercalation of lithium ions (Li + ) and sodium ions (Na + ) is of great significance for the superb lithium – sodium storage capacities. Biomass‐derived carbon materials with affluent porosity have been widely studied as anodes for lithium‐ion batteries (LIBs) and sodium‐ion batteries (SIBs). However, it remains unexplored to further enhance the stability and utilization of the porous carbon skeleton during cycles. Here, a lotus stems derived porous carbon (LPC) with graphene quantum dots (GQDs) and intrinsic carbon nanowires framework (CNF) is successfully fabricated by a self‐template method. The LPC anodes show remarkable Li + and Na + storage performance with ultrahigh capacity (738 mA h g −1 for LIBs and 460 mA h g −1 for SIBs at 0.2 C after 300 cycles, 1C≈372 mA h g −1 ) and excellent long‐term stability. Structural analysis indicates that the CNFs‐supported porous structure and internal GQDs with excellent electrical conductivity contribute significantly to the dominant capacitive storage mechanism in LPC. This work provides new perspectives for developing advanced carbon‐based materials for multifunctional batteries with improved stability and utilization of porous carbon frameworks during cycles.