Direct Z‐Scheme Heterostructure of Vertically Oriented SnS2 Nanosheet on BiVO4 Nanoflower for Self‐Powered Photodetectors and Water Splitting

Abstract The construction of nanostructured Z‐scheme heterostructure is a powerful strategy for realizing high‐performance photoelectrochemical (PEC) devices such as self‐powered photodetectors and water splitting. Considering the band structure and internal electric field direction, BiVO 4 is a promising candidate to construct SnS 2 ‐based heterostructure. Herein, the direct Z‐scheme heterostructure of vertically oriented SnS 2 nanosheet on BiVO 4 nanoflower is rationally fabricated for efficient self‐powered PEC photodetectors. The Z‐scheme heterostructure is identified by ultraviolet photoelectron spectroscopy, photoluminescence spectroscopy, PEC measurement, and water splitting. The SnS 2 /BiVO 4 heterostructure shows a superior photodetection performance such as excellent photoresponsivity (10.43 mA W −1 ), fast response time (6 ms), and long‐term stability. Additionally, by virtue of efficient Z‐scheme charge transfer and unique light‐trapping nanostructure, the SnS 2 /BiVO 4 heterostructure also displays a remarkable photocatalytic hydrogen production rate of 54.3 µmol cm −2 h −1 in Na 2 SO 3 electrolyte. Furthermore, the synergistic effect between photo‐activation and bias voltage further improves the PEC hydrogen production rate of 360 µmol cm −2 h −1 at 0.8 V, which is an order of magnitude above the BiVO 4 . The results provide useful inspiration for designing direct Z‐scheme heterostructures with special nanostructured morphology to signally promote the performance of PEC devices.