反离子
阳离子聚合
光催化
激发态
光化学
化学
可见光谱
反应性(心理学)
配体(生物化学)
催化作用
分子
材料科学
离子
高分子化学
有机化学
原子物理学
物理
光电子学
病理
受体
医学
生物化学
替代医学
作者
Juliette Zanzi,Zachary Pastorel,Carine Duhayon,Elise Lognon,Christophe Coudret,Antonio Monari,Isabelle M. Dixon,Yves Canac,Michaël Smietana,Olivier Baslé
出处
期刊:JACS Au
[American Chemical Society]
日期:2024-07-24
卷期号:4 (8): 3049-3057
被引量:7
标识
DOI:10.1021/jacsau.4c00384
摘要
Photocatalysis that uses the energy of light to promote chemical transformations by exploiting the reactivity of excited-state molecules is at the heart of a virtuous dynamic within the chemical community. Visible-light metal-based photosensitizers are most prominent in organic synthesis, thanks to their versatile ligand structure tunability allowing to adjust photocatalytic properties toward specific applications. Nevertheless, a large majority of these photocatalysts are cationic species whose counterion effects remain underestimated and overlooked. In this report, we show that modification of the X counterions constitutive of [Ru(bpy)
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