Selective CO2Electroreduction to Ethanol over a Carbon‐Coated CuOxCatalyst

Abstract The design of efficient copper(Cu)‐based catalysts is critical for CO 2 electroreduction into multiple carbon products. However, most Cu‐based catalysts are favorable for ethylene production while selective production of ethanol with high Faradaic efficiency and current density still remains a great challenge. Herein, we design a carbon‐coated CuO x (CuO x @C) catalyst through one‐pot pyrolysis of Cu‐based metal‐organic framework (MOF), which exhibits high selectivity for CO 2 electroreduction to ethanol with Faradaic efficiency of 46 %. Impressively, the partial current density of ethanol reaches 166 mA cm −2 , which is higher than that of most reported catalysts. Operando Raman spectra indicate that the carbon coating can efficiently stabilize Cu + species under CO 2 electroreduction conditions, which promotes the C−C coupling step. Density functional theory (DFT) calculations reveal that the carbon layer can tune the key intermediate *HOCCH goes the hydrogenation pathway toward ethanol production.