摘要
Chapter 10 Microwave- and Ultrasound-Assisted Synthesis of Metal-Organic Frameworks ( MOF ) and Covalent Organic Frameworks ( COF ) Sanjit Gaikwad, Sanjit Gaikwad Changwon National University, Department of Chemical Engineering, Changwon-Si, Gyeongsangnam-do, 51140 South KoreaSearch for more papers by this authorSangil Han, Sangil Han Changwon National University, Department of Chemical Engineering, Changwon-Si, Gyeongsangnam-do, 51140 South KoreaSearch for more papers by this author Sanjit Gaikwad, Sanjit Gaikwad Changwon National University, Department of Chemical Engineering, Changwon-Si, Gyeongsangnam-do, 51140 South KoreaSearch for more papers by this authorSangil Han, Sangil Han Changwon National University, Department of Chemical Engineering, Changwon-Si, Gyeongsangnam-do, 51140 South KoreaSearch for more papers by this author Book Editor(s):Dakeshwar Kumar Verma, Dakeshwar Kumar Verma Govt. Digvijay Autonomous Postgraduate College, Department of Chemistry, Rajnandgaon, 491441 Chhattisgarh, IndiaSearch for more papers by this authorChandrabhan Verma, Chandrabhan Verma Khalifa University of Science and Technology, Department of Chemical Engineering, P.O. Box, Abu Dhabi, 127788 United Arab EmiratesSearch for more papers by this authorPaz Otero Fuertes, Paz Otero Fuertes University of Vigo Faculty of Food Science and Technology, Analytical and Food Chemistry Department, Ourense, 32004 SpainSearch for more papers by this author First published: 28 March 2024 https://doi.org/10.1002/9783527844494.ch10 AboutPDFPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShareShare a linkShare onEmailFacebookTwitterLinkedInRedditWechat Summary Microwave- and ultrasound-assisted synthesis techniques have emerged as a promising approach for the rapid and efficient preparation of metal–organic frameworks (MOFs) and covalent organic frameworks (COFs). This approach has shown numerous advantages over conventional synthesis methods, including shorter reaction times, higher yields, and greater purity of products. In this chapter, we will provide a complete outline of the recent developments in microwave- and ultrasound-assisted techniques of MOF and COF synthesis. We discuss the fundamental principles and the synthesis mechanisms of microwave- and ultrasound-assisted synthesis, and the key factors that influence the formation of these materials. Moreover, we highlight the applications of MOFs and COFs in various fields, such as energy storage and conversion, catalysis, CO 2 capture, and sensing. Finally, we provide an outlook on the future prospects of microwave- and ultrasound-assisted synthesis of MOFs and COFs as well as the challenges and opportunities. References Lahcen , A.A. , Surya , S.G. , Beduk , T. et al. ( 2022 ). Metal–organic frameworks meet molecularly imprinted polymers: insights and prospects for sensor applications . ACS Appl. Mater. Interfaces 14 ( 44 ): 49399 – 49424 . 10.1021/acsami.2c12842 CASPubMedGoogle Scholar Mason , J.A. , Veenstra , M. , and Long , J.R. ( 2014 ). Evaluating metal–organic frameworks for natural gas storage . Chem. Sci. 5 ( 1 ): 32 – 51 . 10.1039/C3SC52633J CASPubMedWeb of Science®Google Scholar Wang , S. , Yang , Y. , Liang , X. et al. ( 2023 ). Ultrathin ionic COF membrane via polyelectrolyte-mediated assembly for efficient co 2 separation . Adv. Funct. Mater. 2300386 . 10.1002/adfm.202300386 Google Scholar Qian , Q. , Asinger , P.A. , Lee , M.J. et al. ( 2020 ). MOF-based membranes for gas separations . Chem. Rev. 120 ( 16 ): 8161 – 8266 . 10.1021/acs.chemrev.0c00119 CASPubMedWeb of Science®Google Scholar Du , Y.-X. , Zhou , Y.-T. , and Zhu , M.-Z. ( 2023 ). Co-based MOF derived metal catalysts: from nano-level to atom-level . Tungsten 1 – 16 . Google Scholar Sun , M. , Liu , Z. , Wu , L. et al. ( 2023 ). Bioorthogonal-activated in situ vaccine mediated by a COF-based catalytic platform for potent cancer immunotherapy . J. Am. Chem. Soc. 145 : 5330 – 5341 . 10.1021/jacs.2c13010 CASPubMedGoogle Scholar Liu , X. , Huang , D. , Lai , C. et al. ( 2019 ). Recent advances in covalent organic frameworks (COFs) as a smart sensing material . Chem. Soc. Rev. 48 ( 20 ): 5266 – 5302 . 10.1039/C9CS00299E CASPubMedWeb of Science®Google Scholar Liu , Y. , Chen , L. , Yang , L. et al. ( 2023 ). Porous framework materials for energy & environment relevant applications: a systematic review . Green Energy Environ. 9 : 217 – 310 . 10.1016/j.gee.2022.12.010 Google Scholar Wu , Y. and Weckhuysen , B.M. ( 2021 ). Separation and purification of hydrocarbons with porous materials . Angew. Chem. Int. Ed. 60 ( 35 ): 18930 – 18949 . 10.1002/anie.202104318 CASPubMedWeb of Science®Google Scholar Zhang , S. , Wang , J. , Zhang , Y. et al. ( 2021 ). Applications of water-stable metal-organic frameworks in the removal of water pollutants: a review . Environ. Pollut. 291 : 118076 . 10.1016/j.envpol.2021.118076 CASPubMedWeb of Science®Google Scholar Wei , H. , Chai , S. , Hu , N. et al. ( 2015 ). The microwave-assisted solvothermal synthesis of a crystalline two-dimensional covalent organic framework with high CO 2 capacity . Chem. Commun. 51 ( 61 ): 12178 – 12181 . 10.1039/C5CC04680G CASPubMedWeb of Science®Google Scholar Kamal , K. , Bustam , M.A. , Ismail , M. et al. ( 2020 ). Optimization of washing processes in solvothermal synthesis of nickel-based MOF-74 . Materials 13 ( 12 ): 2741 . 10.3390/ma13122741 CASPubMedWeb of Science®Google Scholar Feng , S.H. and Li , G.H. ( 2017 ). Chapter 4 - Hydrothermal and solvothermal syntheses . In: Modern Inorganic Synthetic Chemistry , 2 e (ed. R. Xu and Y. Xu ), 73 – 104 . Amsterdam : Elsevier . 10.1016/B978-0-444-63591-4.00004-5 Google Scholar Chen , W. , Du , L. , and Wu , C. ( 2020 ). Hydrothermal synthesis of MOFs . In: Metal-Organic Frameworks for Biomedical Applications , 141 – 157 . Elsevier . 10.1016/B978-0-12-816984-1.00009-3 Google Scholar Chalati , T. , Horcajada , P. , Gref , R. et al. ( 2011 ). Optimisation of the synthesis of MOF nanoparticles made of flexible porous iron fumarate MIL-88A . J. Mater. Chem. 21 ( 7 ): 2220 – 2227 . 10.1039/C0JM03563G CASWeb of Science®Google Scholar Łuczak , J. , Kroczewska , M. , Baluk , M. et al. ( 2023 ). Morphology control through the synthesis of metal-organic frameworks . Adv. Colloid Interface Sci. 102864 . 10.1016/j.cis.2023.102864 PubMedGoogle Scholar Gaikwad , S. , Kim , S.-J. , and Han , S. ( 2020 ). Novel metal–organic framework of UTSA-16 (Zn) synthesized by a microwave method: outstanding performance for CO 2 capture with improved stability to acid gases . J. Ind. Eng. Chem. 87 : 250 – 263 . 10.1016/j.jiec.2020.04.015 CASWeb of Science®Google Scholar Gaikwad , S. and Han , S. ( 2019 ). A microwave method for the rapid crystallization of UTSA-16 with improved performance for CO 2 capture . Chem. Eng. J. 371 : 813 – 820 . 10.1016/j.cej.2019.04.112 CASWeb of Science®Google Scholar Khan , N.A. and Jhung , S.H. ( 2015 ). Synthesis of metal-organic frameworks (MOFs) with microwave or ultrasound: rapid reaction, phase-selectivity, and size reduction . Coord. Chem. Rev. 285 : 11 – 23 . 10.1016/j.ccr.2014.10.008 CASWeb of Science®Google Scholar Mu , X. , Zhan , J. , Feng , X. et al. ( 2018 ). Exfoliation and modification of covalent organic frameworks by a green one-step strategy: Enhanced thermal, mechanical and flame retardant performances of biopolymer nanocomposite film . Composites Part A 110 : 162 – 171 . 10.1016/j.compositesa.2018.04.030 CASWeb of Science®Google Scholar Mao , H. , Li , S.-H. , Zhang , A.-S. et al. ( 2021 ). Furfural separation from aqueous solution by pervaporation membrane mixed with metal organic framework MIL-53 (Al) synthesized via high efficiency solvent-controlled microwave . Sep. Purif. Technol. 272 : 118813 . 10.1016/j.seppur.2021.118813 CASGoogle Scholar Vaitsis , C. , Sourkouni , G. , and Argirusis , C. ( 2019 ). Metal organic frameworks (MOFs) and ultrasound: a review . Ultrason. Sonochem. 52 : 106 – 119 . 10.1016/j.ultsonch.2018.11.004 CASPubMedWeb of Science®Google Scholar Masoomi , M.Y. , Bagheri , M. , and Morsali , A. ( 2016 ). High adsorption capacity of two Zn-based metal–organic frameworks by ultrasound assisted synthesis . Ultrason. Sonochem. 33 : 54 – 60 . 10.1016/j.ultsonch.2016.04.013 CASPubMedWeb of Science®Google Scholar Yao , Y. , Pan , Y. , and Liu , S. ( 2020 ). Power ultrasound and its applications: a state-of-the-art review . Ultrason. Sonochem. 62 : 104722 . 10.1016/j.ultsonch.2019.104722 CASPubMedWeb of Science®Google Scholar Pollet , B.G. and Ashokkumar , M. ( 2019 ). Introduction to Ultrasound, Sonochemistry and Sonoelectrochemistry . Springer Nature . 10.1007/978-3-030-25862-7 Google Scholar Zhang , F. , Zhou , T. , Liu , Y. , and Leng , J. ( 2015 ). Microwave synthesis and actuation of shape memory polycaprolactone foams with high speed . Sci. Rep. 5 ( 1 ): 1 – 12 . Google Scholar Chatel , G. ( 2019 ). Sonochemistry in nanocatalysis: the use of ultrasound from the catalyst synthesis to the catalytic reaction . Curr. Opin. Green Sustainable Chem. 15 : 1 – 6 . 10.1016/j.cogsc.2018.07.004 Web of Science®Google Scholar Baumann , A.E. , Burns , D.A. , Liu , B. , and Thoi , V.S. ( 2019 ). Metal-organic framework functionalization and design strategies for advanced electrochemical energy storage devices . Commun. Chem. 2 ( 1 ): 86 . 10.1038/s42004-019-0184-6 Web of Science®Google Scholar Li , G. , Xia , L. , Dong , J. et al. ( 2020 ). Chapter 10 - Metal-organic frameworks . In: Solid-Phase Extraction (ed. C.F. Poole ), 285 – 309 . Elsevier . 10.1016/B978-0-12-816906-3.00010-8 Google Scholar Zhou , H.-C. , Long , J.R. , and Yaghi , O.M. ( 2012 ). Introduction to Metal–Organic Frameworks , 673 – 674 . ACS Publications . Google Scholar MacGillivray , L.R. ( 2010 ). Metal-organic Frameworks: Design and Application . Wiley . 10.1002/9780470606858 Google Scholar Kitagawa , S. ( 2014 ). Metal–organic frameworks (MOFs) . Chem. Soc. Rev. 43 ( 16 ): 5415 – 5418 . 10.1039/C4CS90059F PubMedWeb of Science®Google Scholar Ha , J. , Lee , J.H. , and Moon , H.R. ( 2020 ). Alterations to secondary building units of metal–organic frameworks for the development of new functions . Inorg. Chem. Front. 7 ( 1 ): 12 – 27 . 10.1039/C9QI01119F CASGoogle Scholar Schoedel , A. ( 2020 ). Secondary building units of MOFs . In: Metal-Organic Frameworks for Biomedical Applications , 11 – 44 . Elsevier . 10.1016/B978-0-12-816984-1.00003-2 Google Scholar Cai , G. , Yan , P. , Zhang , L. et al. ( 2021 ). Metal–organic framework-based hierarchically porous materials: synthesis and applications . Chem. Rev. 121 ( 20 ): 12278 – 12326 . 10.1021/acs.chemrev.1c00243 CASPubMedWeb of Science®Google Scholar Gaikwad , R. , Gaikwad , S. , and Han , S. ( 2022 ). Bimetallic UTSA-16 (Zn, X; X= Mg, Mn, Cu) metal organic framework developed by a microwave method with improved CO 2 capture performances . J. Ind. Eng. Chem. 111 : 346 – 355 . 10.1016/j.jiec.2022.04.016 CASWeb of Science®Google Scholar Gaikwad , R. , Gaikwad , S. , Kim , Y. , and Han , S. ( 2021 ). Electrospun fiber mats with multistep seeded growth of UTSA-16 metal organic frameworks by microwave reaction with excellent CO 2 capture performance . Microporous Mesoporous Mater. 323 : 111233 . 10.1016/j.micromeso.2021.111233 CASWeb of Science®Google Scholar Jhung , S.-H. , Lee , J.-H. , and Chang , J.-S. ( 2005 ). Microwave synthesis of a nanoporous hybrid material, chromium trimesate . Bull. Korean Chem. Soc. 26 ( 6 ): 880 – 881 . 10.5012/bkcs.2005.26.6.880 CASGoogle Scholar Aguiar , L.W. , da Silva , C.T.P. , de Lima , H.H.C. et al. ( 2018 ). Evaluation of the synthetic methods for preparing metal organic frameworks with transition metals . AIMS Mater. Sci. 5 ( 3 ): 467 – 478 . 10.3934/matersci.2018.3.467 CASGoogle Scholar Ren , J. , Segakweng , T. , Langmi , H.W. et al. ( 2014 ). Microwave-assisted modulated synthesis of zirconium-based metal–organic framework (Zr-MOF) for hydrogen storage applications . Int. J. Mater. Res. 105 ( 5 ): 516 – 519 . 10.3139/146.111047 CASGoogle Scholar Minh , T.T. and Thien , T.V. ( 2017 ). Synthesis of metal-organic framework-199: comparison of microwave process and solvothermal process . Hue Univ. J. Sci. Nat. Sci. 126 ( 1C ): 107 – 116 . Google Scholar Taddei , M. , Dau , P.V. , Cohen , S.M. et al. ( 2015 ). Efficient microwave assisted synthesis of metal–organic framework UiO-66: optimization and scale up . Dalton Trans. 44 ( 31 ): 14019 – 14026 . 10.1039/C5DT01838B CASPubMedGoogle Scholar Gusain , D. and Bux , F. ( 2019 ). Synthesis of magnesium based metal organic framework by microwave hydrothermal process . Inorg. Chem. Commun. 101 : 172 – 176 . 10.1016/j.inoche.2019.01.034 CASGoogle Scholar Liang , W. and D'Alessandro , D.M. ( 2013 ). Microwave-assisted solvothermal synthesis of zirconium oxide based metal–organic frameworks . Chem. Commun. 49 ( 35 ): 3706 – 3708 . 10.1039/c3cc40368h CASPubMedWeb of Science®Google Scholar Wang , X.-F. , Zhang , Y.-B. , Huang , H. et al. ( 2008 ). Microwave-assisted solvothermal synthesis of a dynamic porous metal-carboxylate framework . Cryst. Growth Des. 8 ( 12 ): 4559 – 4563 . 10.1021/cg800623v CASGoogle Scholar Chen , C. , Feng , X. , Zhu , Q. et al. ( 2019 ). Microwave-assisted rapid synthesis of well-shaped MOF-74 (Ni) for CO 2 efficient capture . Inorg. Chem. 58