聚酰亚胺
堆积
膜
材料科学
化学工程
动态力学分析
高分子化学
溶胶凝胶
流变学
溶剂
相变
聚合物
化学
有机化学
复合材料
纳米技术
图层(电子)
热力学
物理
工程类
生物化学
作者
Jiaxiang Wen,Senjie Jiang,Junkang Wang,Xueqing Li,Zhijun Bi,Y. Jiang,Long Fan,Lihuan Wang,Yanran Wu,Feng Gan
出处
期刊:Polymer
[Elsevier]
日期:2023-06-01
卷期号:278: 126006-126006
被引量:3
标识
DOI:10.1016/j.polymer.2023.126006
摘要
Constructing fully rigid chain polyimides with reversible sol-gel/gel-sol transition is significant for developing high-performance and functional materials. π-π stacking, a typical weak interaction, has attracted great interest in producing functional gels, but less has been reported in polyimide organogels. This work developed new polyimide organogels using π-π interactions by incorporating bisbenzoxazole moieties with fully coplanar structures in polyimides. The reversible sol-gel transition behavior with temperature and strain response was systematically studied using rheological methods. DFT simulations, temperature-dependent NMR, UV–Vis, and fluorescence spectroscopy results confirmed the existence of the dynamic π-π interactions in polyimides. Based on the success, we further combined sol-gel methods and non-solvent phase separation methods to prepare a new type of nanofiltration (NF) membranes. The resulting NF membranes showed a higher rejection of methylene blue (rejections of 99.6%) and a good permeability of sodium salt (rejections of 5.1–7.7%), showing great promise for selective filtration of industrial dye wastewater.
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