Enhanced Hydrogen Evolution Reaction in Alkaline Media via Ruthenium–Chromium Atomic Pairs Modified Ruthenium Nanoparticles

are the main active sites for the alkaline HER, facilitating the rate-determining steps of water adsorption and dissociation. Moreover, the Ru-Cr interaction also plays a vital role in modulating hydrogen desorption. This study presents a synergistic approach by rationally combining single atoms, atomic pairs, and nanoparticles with optimized EMSI effects to advance the development of efficient electrocatalysts for alkaline HER.