蒽
荧光
分子
量子产额
分子间力
光化学
猝灭(荧光)
氢键
化学
发光
甲基丙烯酸甲酯
晶体工程
材料科学
聚合物
有机化学
物理
光电子学
单体
量子力学
作者
Liang Zhang,Ding Liu,Shiyuan Zhou,Feng Zhang,Peiyang Gu
标识
DOI:10.1016/j.dyepig.2022.110991
摘要
Luminescent small molecules in the solid states are of significant importance for organic light-emitting diodes, cell images, fluorescent probes and sensors, owing to the low cost, low toxicity and chemical stability. Herein, two anthracene-based molecules with the same skeleton, but differing in the end group namely M-MMA and M-4VB (methyl methacrylate for M-MMA, 4-vinylbenzeyl for M-4VB) were successfully designed and synthesized. M-4VB exhibits strong green fluorescence with high quantum yield (37%) in the solid state and excellent aggregation-induced emission (AIE) behavior in DMF/water mixtures, while M-MMA shows relatively weak emission. The crystal structures of both M-MMA and M-4VB were successfully obtained in THF/ethanol mixtures. The more rigid environment and stronger intermolecular hydrogen bonding interactions contribute to the enhanced emission behavior of M-4VB at both solid state and aggregation state. The novel and simple synthesis strategy in this work provides a new approach to the transformation from aggregation-caused quenching to AIE molecules with enhanced emission behavior in the solid state.
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