石墨氮化碳
光催化
材料科学
可见光谱
光致发光
光子上转换
表面等离子共振
纳米复合材料
制氢
氮化碳
化学工程
纳米颗粒
纳米技术
光化学
光电子学
氢
碳纤维
量子点
复合数
化学
催化作用
兴奋剂
复合材料
有机化学
工程类
标识
DOI:10.1016/j.apcatb.2017.03.005
摘要
To make the best and highest use of broad spectrum solar energy remains a tremendous challenge and the main target in the photocatalytic area. A novel promising photocatalyst supported on surface plasmon resonance of Ag nanoparticles (NPs) and upconversion photoluminescence property from carbon quantum dots (CQDs) is reported to improve broad spectrum absorption and photoinduced charge transfer of graphitic carbon nitride (g-C3N4) in the photo-driven H2 production for the first time. Here the new-styled nanocomposites not only have more prominent UV–vis photocatalytic ability, also can harness near-infrared light to trigger hydrogen evolution in aqueous solution. Meanwhile, Ag NPs and CQDs serve as electron-reservoirs, which stimulate the separation of photo-generated electron-holes, enhancing quantum efficiency of g-C3N4. Remarkably, the most notable photocatalytic hydrogen generation as high as 626.93 μmol g−1 h−1 under visible light, which is about 6.7 and 2.8 times higher than pure g-C3N4 and the best CQDs/g-C3N4 composite respectively, was achieved upon 6 mL CQDs/g-C3N4 (6CCN) loaded with 3 wt% Ag. Moreover, a facile method is designed to prepare Ag/CQDs/g-C3N4 photocatalysts, and their chemical composition, morphologies, optical properties and stability were characterized methodically.
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