氟化物
材料科学
固态
离子
工程物理
无机化学
光电子学
化学
工程类
有机化学
作者
Irshad Mohammad,Raiker Witter,Maximilian Fichtner,M. Anji Reddy
出处
期刊:ACS applied energy materials
[American Chemical Society]
日期:2018-08-03
卷期号:1 (9): 4766-4775
被引量:65
标识
DOI:10.1021/acsaem.8b00864
摘要
Fluoride ion batteries (FIBs) are among interesting electrochemical energy storage systems that are being considered as alternatives to lithium-ion batteries (LIBs). FIB offers high specific energy and energy density, thermal stability, and safety. Despite the advantages posed by the FIBs, several challenges need to be addressed to realize its full potential. We have been working on various aspects related to FIB with the aim of developing sustainable fluoride ion batteries. So far rechargeable FIBs have been demonstrated only at an elevated temperature like 150 °C and above. Here, for the first time, we demonstrate room-temperature (RT) rechargeable fluoride-ion batteries using BaSnF4 as fluoride transporting solid electrolyte. The high ionic conductivity of tetragonal BaSnF4 (3.5 × 10–4 S cm–1) enables the building of RT FIB. We built fluoride ion batteries using Sn and Zn as anodes and BiF3 as a cathode. We have investigated the electrochemical properties of two different electrochemical cells, Sn/BaSn...
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