材料科学
石墨烯
阳极
氧化物
电化学
电极
纳米颗粒
金属
离子
碳纤维
钾
纳米技术
化学工程
复合数
复合材料
有机化学
化学
工程类
物理化学
冶金
作者
Qiao Xiaohua,Chaoqun Niu,Dankui Liao,Zhonghui Chen,Lixia Sun,Yuxi Xu
标识
DOI:10.1002/adfm.202105145
摘要
Abstract Herein, a simple but effective self‐growth strategy to simultaneously modulate the interlayer distance and lyophilicity of graphene layers, which results in ultrahigh potassium‐storage performances for carbon materials, is reported. This strategy involves the uniform adsorption of individual metal ions on the oxygen‐containing groups on graphene oxide via electrostatic/coordination interactions and in situ self‐conversion reaction between the metal ions and the oxygen‐containing groups to form lyophilic ultrasmall metal oxide nanoparticles modified/intercalated graphene skeleton (OM‐G) with precisely regulated interlayer distance. The synergistic effect of expanded interlayer distance and enhanced lyophilicity is revealed for the first time to significantly reduce the ion diffusion barrier and enhance ion transport kinetics by experimental and theoretical analysis. As a result, such unique OM‐G monolith as free‐standing anode for potassium‐ion battery (PIB) delivered an ultrahigh reversible capability of 496.4 mAh g −1 at 0.1 A g −1 , excellent rate capability (306.6 mAh g −1 at 10 A g −1 ), and remarkable long‐term cycling stability (96.3% capacity retention over 2000 cycles at 1 A g −1 ), which are not only much better than those of previous graphene/carbon materials but also among the best performances for all PIB anodes ever reported. This study provides new fundamental insights for boosting the electrochemical properties of electrode materials.
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