SiO2TiO2 mixed oxide with 20 wt% TiO2 was prepared by solgel one step hydrolysis method with lowcost TiCl4 as precursor and the effect of calcination temperature was also studied The properties of the samples calcined at the different temperature were investigated by N2 physisortion, FTIR and XRD The specific area of the prepared mixed oxide could be up to 6617m2/g and still possess 11m2/g after calcined at 1100℃ The mixed oxide had good stability and calcination in a wide range of temperature didn't result in the break of TiOSi band It kept in the form of amorphous even if being calcined at high temperature