Scalable Photocatalyst Panels for Photoreforming of Plastic, Biomass and Mixed Waste in Flow

Abstract Solar‐driven reforming uses sunlight and a photocatalyst to generate H 2 fuel from waste at ambient temperature and pressure. However, it faces practical scaling challenges such as photocatalyst dispersion and recyclability, competing light absorption by the waste solution, slow reaction rates and low conversion yields. Here, the immobilisation of a noble‐metal‐free carbon nitride/nickel phosphide (CN x |Ni 2 P) photocatalyst on textured glass is shown to overcome several of these limitations. The 1 cm 2 CN x |Ni 2 P panels photoreform plastic, biomass, food and mixed waste into H 2 and organic molecules with rates comparable to those of photocatalyst slurries. Furthermore, the panels enable facile photocatalyst recycling and novel photoreactor configurations that prevent parasitic light absorption, thereby promoting H 2 production from turbid waste solutions. Scalability is further verified by preparing 25 cm 2 CN x |Ni 2 P panels for use in a custom‐designed flow reactor to generate up to 21 μmol H m −2 h −1 under “real‐world” (seawater, low sunlight) conditions. The application of inexpensive and readily scalable CN x |Ni 2 P panels to photoreforming of a variety of real waste streams provides a crucial step towards the practical deployment of this technology.