A H2S and I− dual-responsive supramolecular polymer constructed via pillar[5]arene-based host–guest interactions and metal coordination

A supramolecular polymer was designed and prepared by self-assembly of a pillar[5]arene dimer (AA-type), constructed from Ag-coordination, and a homoditopic (BB-type) guest (G). The supramolecular polymer displayed H₂S and I⁻ dual responsiveness due to the sensitivity of Ag⁺ to H₂S and I⁻.