乙二醇
双金属片
钨
催化作用
过渡金属
纤维素
选择性
氢解
铑
金属
乙烯
高分子化学
材料科学
无机化学
有机化学
化学
作者
Ming‐Yuan Zheng,Aiqin Wang,Na Ji,Jifeng Pang,Xiaodong Wang,Tao Zhang
出处
期刊:Chemsuschem
[Wiley]
日期:2009-12-08
卷期号:3 (1): 63-66
被引量:313
标识
DOI:10.1002/cssc.200900197
摘要
Tungsten-based bimetallic catalysts (W–M(8,9,10); where M(8,9,10) is Ni, Pd, Pt, Ir, Ru, or Rh) are found to be highly active and selective for the formation of ethylene glycol from cellulose. The cooperation between CC cracking reactions over metallic tungsten and the hydrogenation of unsaturated intermediates over the transition metals M(8,9,10) results in a particularly high selectivity towards ethylene glycol, up to 75 %. Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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