化学
激进的
反应性(心理学)
光催化
烷氧基
光化学
光催化
组合化学
有机化学
催化作用
烷基
医学
病理
替代医学
作者
Jingjing Guo,Anhua Hu,Zhiwei Zuo
标识
DOI:10.1016/j.tetlet.2018.04.060
摘要
Alkoxy radicals have been intensively studied as versatile synthetic intermediates with well-established reactivity and selectivity. Due to the difficulties associated with the generation of these transient and high-energy radicals, the utilization of the unique reactivity of alkoxy radicals in catalytic platforms has become a rather challenging task. Recent studies on the alkoxy radical-mediated transformations have benefited tremendously from advances in modern photoredox catalysis. In this digest, we aim to highlight reported transformations that utilize alkoxy radicals in a photocatalytic fashion, in particular, underline novel catalytic platforms which we anticipate will find broad application in the near future.
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