光催化
光化学
可见光谱
材料科学
异质结
卟啉
载流子
石墨氮化碳
共轭体系
聚合物
化学
锌
光电子学
催化作用
有机化学
复合材料
冶金
作者
Wen Zou,Xiaohui Liu,Can Xue,Xiantai Zhou,Haiyang Yu,Ping Fan,Hongbing Ji
标识
DOI:10.1016/j.apcatb.2020.119863
摘要
Graphitic carbon nitride (g C3N4, CN) has been widely used as a photocatalyst due to its high stability and suitable band gap. However, its further development is limited due to inefficient light harvesting and rapid recombination of photogenerated carriers. In this study, a visible-light-responsive zinc porphyrin (ZnP)/CN heterojunction photocatalyst was synthesized by the combination of CN and a zinc-porphyrin-conjugated microporous polymer (ZnP-CMP). ZnP/CN exhibited excellent photocatalytic activity for the oxidative coupling of amines to imines under visible-light irradiation. The efficiency of the as-developed photocatalyst was 25 times greater than that of CN and about 2 times greater than that of ZnP-CMP. The significantly enhanced catalytic efficiency was attributed to the promotion of visible-light harvesting and photogenerated charge mobility via the introduction of ZnP-CMP. The ZnP/CN heterojunction photocatalyst also exhibited excellent broad substrate scope, stability, and reusability.
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