化学
氧化还原
偶联反应
催化作用
烷基化
甲烷氧化偶联
铜
光催化
有机合成
光化学
碳纤维
组合化学
光催化
有机化学
复合材料
复合数
材料科学
作者
Yan Xiong,Sijia Li,Haijing Xiao,Guozhu Zhang
出处
期刊:Synthesis
[Georg Thieme Verlag KG]
日期:2021-06-22
卷期号:53 (23): 4327-4340
被引量:14
摘要
Abstract In recent years, visible-light-mediated copper photocatalysis has emerged as an attractive strategy for the diverse construction of basic bonds in an ecologically benign and cost-effective fashion. The intense activity in these areas has been stimulated by the distinctive properties of copper photocatalysts and has led to the rapid development and expansion of their applications. In this review, we focus on a series of significant achievements in the use of copper complexes as standalone photocatalysts in organic reactions to exhibit their high flexibility and potential in synthetic chemistry. 1 Introduction 2 Redox Coupling Reactions 2.1 Carbon–Nitrogen Redox Coupling Reactions 2.2 Carbon–Carbon Redox Coupling Reactions 3 Oxidative Coupling Reactions 4 Difunctionalization of Olefins 5 C–H Bond Functionalization 6 Radical Alkylation of Imines 7 Conclusions and Outlook
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