A reduced polyoxometalate-encapsulated organo cobalt modified phosphate framework for improving photocatalytic reduction of CO2

An innovative polyoxometalate-based cobalt-modified organophosphate framework was synthesized and applied for CO 2 reduction for a high selectivity of 94.5% and an ultra-high CO production rate of 13 676 μmol g −1 h −1 in photocatalytic investigations.