Distal iodine migration of arylalkynes via cyclic monoaryliodonium salts
化学
碘
有机化学
作者
Kai Huang,Xiao‐Zeng You,Bingling Luo,Shulin Wen,Dong Mei Zhu
出处
期刊：Organic chemistry frontiers [The Royal Society of Chemistry] 日期：2024-01-01卷期号：11 (5): 1350-1356
标识
DOI：10.1039/d3qo01712e
摘要
A convenient synthesis of cyclic monoaryliodonium salts with readily obtained iodoethynylarenes is presented. ortho -Iodoarylacetylenes and 1,3-diynes are afforded in sequential one-pot iodine migration reactions directly from iodoethynylarenes via the in situ formed cyclic monoaryliodoniums.
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